ligand field
英
美 [ˈlɪgənd fiːld]
网络 配位场; 配体场
双语例句
- The relative order of σ bonding strength and ligand field splitting en-ergies have been calculated by using the hyperfine coupling constants and g values.
用超精细耦合常数和g值计算了σ键强度以及配位场分裂能次序。 - The presence of hydrate water and free-water modifies the ligand field of central ion Cr(ⅲ), so that the absorption bands of iridescent chromium films are influenced.
结晶水和游离水的存在修改了中心离子Cr（Ⅲ）的配位体场，使得彩虹色铬膜层的吸收谱带受到影响。 - Studies on the ligand field theory ⅲ. analysis of energy spectrum of the d~ 4 and d~ 6 configurations in octahedral field
配位势场理论的研究Ⅲ.d~4，d~6组态正八面体络合物能谱全分析 - Applications of S function Method of Continuous Groups for the Classification of Energy Spectra in Ligand Field
连续群S&函数方法在配位场能谱分类中的应用 - The ligand field stabilization energy ( LFSE) can be obtained from the electron absorption spectrum of the coordination compounds.
配体场稳定化能（LFSE）可以从配合物的电子光谱实验求算出来。 - Application of the Ligand Field Theory to Study the Energy Levels of Electronic Spectra and Molecular Configurations of Complexes of Cobalt(ⅱ) with β-Diketones
应用配位场理论研究β二酮类合钴（Ⅱ）络合物电子光谱能级和分子构型 - Ligand field calculation of the relative displacements of the d band in v_3x system
V3X系d带相对移动量的配位场方法的计算 - By using the ligand field theory and 3d orbits wave radial scaling theory, the d& d transition spectrum is interpreted quantitatively.
应用配位场理论以及3d轨道波函数径向标度理论定量地解释了晶体的电子吸收光谱。 - The unitary group appoach ( uga) to the weak field model of a ligand field ( d~ n ions)
配位场弱场方案的酉群方法（d~N离子） - Energy levels of d~ n system in ligand field of orthorhombic symmetry
正交对称性场中d~N体系的能级 - The d-d transition absorption spectra of the complexes Co ( ad) ( adH) Cl · H2O is analysed. It belong to Cs local symmetry. The ligand field calculation is applied to molecules with Cs point group symmetry.
对Co（ad）（adH）Cl·H2O分子的d－d跃迁吸收光谱，我们进行了分析，指出了它具有Cs局部对称。 - The ligand field energy has been calculated in this paper. Taking two or three terms from the eigenvalue function expansion of intermediate field under condition of neglecting the interaction of different configurations, the result approaching that from total analysis has been obtained.
在忽略电子组态间相互作用下取中间场全分析本征函数展开式中两、三项来计算配位场能级，得到接近全分析的结果，建立了配位场能级相关图； - An improved weak-field coupling scheme in the ligand field theory is proposed.
本文提出了配位场理论的改进的弱场方案。 - The ligand field stabilization, the transition-metal contraction, and the lanthanide contraction are reflected in the relative values of the electronegativity scale.
此外，该标度值的相对大小还能反映配合物的稳定性，过渡金属收缩和镧系元素收缩等性质。 - Taking the effect of centre symmetric ligand field into account, we have proposed 3d-radial wave function which is in the bound state and consists of different bases.
考虑中心对称配体场影响，提出一种不同基混合的束缚态过渡金属离子的3d径向波函数。 - Ligand field theory of f-orbital sandwich complexes
f夹心化合物的配位场理论 - The Raman spectra of KTP single crystal that is an excellent material applicable to the nonlinear optical devices have been obtained. And its features are discussed in some detail in terms of group the-ory, lattice dynamics and ligand field theory.
测量了性能优良的非线性光学材料KTP单晶的Raman谱，并从群论、晶格动力学理论和配位场理论对其特点进行了详细的讨论。 - Second, using Ligand Field Theory accounted for the bleaching mechanism of ART and other tanning agent's.
本文还从配位场理论的角度研究了ART及其它复鞣剂对皮革的漂白机理。 - From this view, by diagonalizing the perturbation energy matrices with trigonal symmetry ligand field, we find that the experimental EPR zero-field splitting parameters a, D, and ( a-F) can be explained reasonably.
从这一观点出发，通过对角化三角场中的微扰能量矩阵，使得ZnS∶Mn2+和ZnS∶Fe3+体系的EPR零场分裂参量α，D和（a-F）的实验值都能得到满意的解释。 - Ligand Field Theoretical Treatment for the Electronic Spectra of Organometallic Complexes CoCl_2 ( PR_3)_2
金属有机络合物CoCl2（PR3）2电子吸收光谱的配位场处理 - LFT ( ligand field theory) and VBT ( valence bond theory) are applied to elucidate why Cr-Al complexes is not enough stable in solution.
并结合配位场理论和价键理论解释了Cr-Al异金属配合物不稳定的原因。 - Because of the disturbance of ligand field, the symmetry of Eu ( DBM) 3phen largely decreased, leading to the increasing of photoluminescent purity.
由于配位场的微扰作用，Eu（DBM）3phen配合物的对称性强烈下降，导致发光纯度提高。 - Coupling coefficients for the group chain of the strong field scheme of the ligand field theory
配位场理论中强场方案群链耦合系数的计算 - A Study of the Theory of Ligand Field for the Rare Earth Compounds& The Transformation of SO ( 3)-D_n
稀土化合物配位场理论的研究&SO（3）-Dn群的变换 - A Computer Program of Perturbational Energy Levels of Ligand Field
配位场微扰能级计算程序设计 - The spherical symmetry component of a ligand field
配体场的球对称分量 - Energy Level Structure of KTbP_4O_12 and Ligand Field Theoretical Calculation
KTbP4O（12）的能级结构及配位场理论计算 - They belong to C_ ( 2V) local symmetry. From the point of view of point-charge model the ligand field semi-quantitative calculation is applied to molecules with C_ ( 2v) point group symmetry.
指出它们均具有C（2v）局部对称性，并从晶体场点电荷模型出发对具有C（2v）对称性点群的分子进行了配位场半定量计算。 - Finally, the ligand field splitting parameter Dq and Racah parameter B are calculated approximately by using UV-UIS spectra.
利用紫外吸收峰近似计算了配体场分裂参数Dq和Racah参数B。